GREEN SYNTHESIS OF SUPERPARAMAGNETIC IRON OXIDE NANOPARTICLE FROM FICUS CARICA FRUIT EXTRACT, CHARACTERIZATION STUDIES AND ITS APPLICATION ON DYE DEGRADATION STUDIES

Authors

  • Tharunya P
  • Subha V
  • KIRUBANANDAN S Dalhousie University
  • Sandhaya S
  • Renganathan S

DOI:

https://doi.org/10.22159/ajpcr.2017.v10i3.15538

Abstract

ABSTRACT
Objective: The synthesis of nanoparticles (NPs) has become a matter of great interest in recent times due to their various advantageous properties
and applications in a variety of fields. Metal NPs are being increasingly used in many sectors, and there is growing interest in the biological and
environmental safety of their production.
Methods: In this study, iron oxide NPs (Fe3O4-NPs) were synthesized from fruits of Ficus carica using a rapid, single step and completely green
biosynthetic method by reduction of ferrous sulfate solution with F. carica ethanolic extract. The prepared Fe3O4-NPs were investigated by X-ray
diffraction, Fourier transform infrared spectroscopy, and ultraviolet-visible spectroscopy.
Results: The report emphasizes the effect of superparamagnetic Fe3O4-NPs on the degradation rate of hazardous dyes acid blue.
Conclusion: To conclude, Fe3O4-NPs were prepared from fruits of F. carica using a rapid, single step and completely green biosynthetic method by
reduction of ferrous sulfate solution with F. carica ethanolic extract.
Keywords: Ficus carica, Ethanolic extract, Reduction, Ferrous sulfate, Superparamagnetic iron oxide nano particles, Dye degradation.

 

Downloads

Download data is not yet available.

References

REFERENCES

Chatterjee K, Sarkar S, Jagajjanani Rao K, Paria S. Core/shell nanoparticles in biomedical applications. Adv Colloid Interface Sci 2014;209:8-39.

Lu AH, Salabas EL, Schüth F. Magnetic nanoparticles: Synthesis, protection, functionalization, and application. Angew Chem Int Ed Engl 2007;46(8):1222-44.

Mody VV, Siwale R, Singh A, Mody HR. Introduction to metallic nanoparticles. J Pharm Bioallied Sci 2010;2(4):282-9.

Gupta AK, Gupta M. Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications. Biomaterials 2005;26(18):3995-4021.

Yeary LW, Ji WM, Love LJ, Thompson JR, Rawn CJ, Phelps TJ. Magnetic properties of biosynthesized magnetitenanoparticles. Magn IEEE Trans 2005;41:4384-9.

Roh Y, Vali H, Phelps TJ, Moon JW. Extracellular synthesis of magnetite and metal-substituted magnetite nanoparticles. J Nanosci Nanotechnol 2006;6(11):3517-20.

Senthil M, Ramesh C. Biogenic synthesis of Fe3O4 nanoparticles using Tridax procumbens leaf extract and its antibacterial activity on Pseudomonas aeruginosa. Digest J Nanomater Bio Struct 2012;7:1655-60.

Manikandan N, Kuzhali SS, Kumuthakalavalli R. Biodegradation of textile dye by using achromobacterxylosoxidans GRIRKNM11 isolated from dye polluted site, Journal of Environ Anal Toxicol 2012;2(160):2.

Sun YP, Li XQ, Zhang WX, Wang HP. A method for the preparation of stable dispersion of zero-valent iron nanoparticles. Colloids Surf A 2008;308:60-6.

Kang SF, Liao CH, Po ST. Decolorization of textile wastewater by photo-fenton oxidation technology. Chemosphere 2000;41(8):1287-94.

Deng Y, Wang L, Yang W, Fu S, Elaissari A. Preparation of magnetic polymeric particles via inverse microemulsion polymerization process. J Magn Magn Mater 2003;257:69-78.

Franger S, Berthet P, Berthon J. Electrochemical synthesis of Fe3O4 nanoparticles in alkaline aqueous solutions containing complexing agents. J Solid State Electrochem 2004;8:218-23.

Hua J, Yong, HQ. Controlled synthesis and magnetic properties of Fe3O4 walnut spherical particles and octahedral microcrystals. Sci Chin Technol Sci 2008;5:1911-20.

Islam N, Phong LV, Jeong JR, Kim CG. A facile route to sonochemical synthesis of magnetic iron oxide (Fe3O4) nanoparticles. J Thin Solid Films 2011;519:8277-9.

Wu W, He Q, Jiang C. Magnetic iron oxide nanoparticles: Synthesis and surface functionalization strategies. Nanoscale Res Lett 2008;3:397-415.

Kulkarni SV, Blackwell CD, Blackard AL, Stackhocese CW, Alexander MW. Textile Dyes and Dyeing Equipment, Classification, Properties and Environmental Aspects. NC (EPA-600/2-85/010). Research Triangle Park, NC: US Environmental Protection Agency; 1985.

Zollinger H. Color Chemistry: Synthesis, Properties and Applications of Organic and Pigments. New York: Wiley-VCH; 1987. p. 543-66.

Saravanan M, Prakash NK, Arasu M, Vijayakumar B, Vincent S. Enhanced antibacterial activity of iron oxide magnetic nanoparticles

Fig. 3: X-ray diffractometer pattern of Iron oxide nanoparticle

Fig. 4: Variation of dye concentration with time reduction in ultraviolet-visible absorption peaks with time

Fig. 5: Iron nanoparticles

Asian J Pharm Clin Res, Vol 10, Issue 3, 2017, 125-128

Tharunya et al.

treated with Argemone mexicana leaf extract: An in vitro study. Mater Res Bull 2013;48:3323-7.

Awwad AM, Salem NM. A green and facile approach for synthesis of magnetite nanoparticles. J Nanosci Nanotechnol 2012;2(6):208-13.

Guo L, Liu G, Hong RY, Li HZ. Preparation and characterization of chitosan poly(acrylic acid) magnetic microspheres. Mar Drugs 2010;8:2212-22.

Frelink T, Visscher W, Veen J. Particle size effect of carbon supported platinum catalysts for the electro oxidation of methanol. J Electroanal Chem 1995;382:65-72.

Falicov LM, Somorjai GA. Correlation between catalytic activity and bonding and coordination number of atoms and molecules on transition metal surfaces: Theory and experimental evidence. Proc Natl Acad Sci India Sect B Biol Sci 1985; 82: 2207-11

Published

01-03-2017

How to Cite

P, T., S. V, K. . S, S. S, and R. S. “GREEN SYNTHESIS OF SUPERPARAMAGNETIC IRON OXIDE NANOPARTICLE FROM FICUS CARICA FRUIT EXTRACT, CHARACTERIZATION STUDIES AND ITS APPLICATION ON DYE DEGRADATION STUDIES”. Asian Journal of Pharmaceutical and Clinical Research, vol. 10, no. 3, Mar. 2017, pp. 125-8, doi:10.22159/ajpcr.2017.v10i3.15538.

Issue

Section

Original Article(s)