AQUEOUS CHEMISTRY OF SOME BIO-METAL (II) COMPLEXES WITH NICOTINIC ACID AND ADENINE


Shardasundaram Sanjay

Abstract


Abstract


 Aqueous  chemistry  of  some  bio-metal complexes of  Cu(II), Ni(II),Co(II), and Cd(II), with nicotinic acid and adenine were investigations pH-metrically on  computer based programme. The mixed ligand complex formation equilibria of these complexes in aqueous solutionhaving constant ionic strength I=0.1 mol/dm3NaNO3 and 37±0.2°C& applied for determination of complexationbehaviour of (1:1) binaryML1&ML2and (1:1:1) ternary ML1L2species. Stability constant have been determined throughthe method suggested by Irving & Rossetti and further refined through Stability Constant of Generalized Species (SCOGS)computer program. The percentage of species distribution curves have been demonstrated with the help of ORIGIN 6.1 software& plotted as a function ofpH. The highest percentage of ternary species of Cu(II)L1L2, is 67.4 at ~6.1 pH,Co(II)L1L2is 82.9 at ~7.3 pH,Cd(II)L1L2is 96.2 at~8-8.2 pH&Ni(II)L1L2is93.2at~7.4 pH which is also determined with the help of software.

Keywords Ternary chelates, bio-metal ions, stability constants, SCOGS.


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About this article

Title

AQUEOUS CHEMISTRY OF SOME BIO-METAL (II) COMPLEXES WITH NICOTINIC ACID AND ADENINE

Date

01-08-2016

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Journal

Innovare Journal of Sciences
VOL 4 ISSUE 4 2016 (AUGUST-SEPTEMBER) Page: 16-19

Online ISSN

2321-5496

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Authors & Affiliations

Shardasundaram Sanjay


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